Antiferromagnetic transition of fayalite under high pressure studied by Mössbauer spectroscopy     

Mitsuhiko Hayashi  Ichiro Tamura  Osamu Shimomura  Hiroshi Sawamoto  Haruki Kawamura 《Physics and Chemistry of Minerals》1987,14(4):341-344

Néel temperature (Tm _N of α-Fe₂SiO₄ (fayalite) was measured as a function of pressure by means of Mössbauer spectroscopy in the pressure range 0–16 Gpa. High pressure was generated using a clamp-type miniature diamond anvil cell which was inserted into a cryostat. The Néel temperature increased linearly with increasing pressure at a rate of dT _N /dp=2.2±0.2 K/GPa. The result is discussed on the basis of the model proposed for the magnetic structure of fayalite by Santoro et al. (1966). The observed dT _N /dp suggests that the superexchange interactions vary as the ?10/3 power of the volume while the volume dependence of the direct exchange interactions is positive and small.  相似文献   

Kinetics of reactions between aqueous sulfates and sulfides in hydrothermal systems   总被引：1，自引：0，他引：1  

Hiroshi Ohmoto  Antonio C. Lasaga 《Geochimica et cosmochimica acta》1982,46(10):1727-1745

The rates of chemical reactions between aqueous sulfates and sulfides are essentially identical to sulfur isotopic exchange rates between them, because both the chemical and isotopic reactions involve simultaneous oxidation of sulfide-sulfur atoms and reduction of sulfate-sulfur. The rate of reaction can be expressed as a second order rate law: R = k·[∑SO₄^2?]·[∑S^2?], where R is the overall rate, k is the rate constant and [∑SO₄^2?] and [∑S^2?] are molal concentrations. We have computed the rate constants from the available experimental data on the partial exchange of sulfur isotopes between aqueous sulfates and sulfides using the rate law established by us: $\text{ln(}\text{α}{}^{\mathrm{e}}\text{? α}\text{α}{}^{\mathrm{e}}\text{? α}{}^0\text{) = ? kt([∑SO}{}_4{}^{\mathrm{2?}}\text{] + [∑S}{}^{\mathrm{2?}}\text{])}$, where t is time and α⁰, α, and α^e are, respectively, the fractionation factors at t = 0 (the initial condition), at the end of experiment, and at equilibrium. The equilibrium fractionation factor can be expressed as: $\text{1000 ln α}{}^{\mathrm{e}}\text{=}\text{6.463 × 10}{}^6\text{T}{}^2\text{+ 0.56 (±.5)}$ (T in Kelvin).The rate constants are strongly dependent on T and pH, but not in as simple a manner as suggested by Igumnov (1976). Our rate constants in Na-bearing hydrothermal solutions decrease by 1 order of magnitude with an increase in pH by 1 unit at pH's less than ~3, remain constant in the pH range of ~4 to ~7, and again decrease at pH >7. The activation energy for the reaction also depends on pH: 18.4 ± 1 kcal/mole at pH = 2, 29.6 ± 1 kcal/mole at pH = 4 to 7, and between 40 and 47 kcal/mole at pH around 9. The observed pH dependence of the rate constant and of the activation energy can be best explained by a model involving thiosulfate molecules as reaction intermediates, in which the intramolecular exchange of sulfur atoms in thiosulfates becomes the rate determining step.The rate constants obtained in this study were used to compute the changes in the isotopic fractionation factors between aqueous sulfates and sulfides during cooling of fluids. Comparisons with data of coexisting sulfate-sulfide minerals in hydrothermal deposits, suggest that simple cooling was not a likely mechanism for coprecipitation of sulfate and sulfide minerals at temperatures below 350°C. Mixing of sulfide-rich solutions with sulfate-rich solutions at or near the depositional sites is a more reasonable process for explaining the observed fractionation.The degree of attainment of chemical equilibrium between aqueous sulfates and sulfides in a hydrothermal system, and the applicability of a_O2-pH type diagrams to mineral deposits, depends on the ∑S content and the thermal history of the fluid, which in turn is controlled by the flow rate and the thermal gradient in the system.The rates of sulfate reduction by non-bacterial processes involving a variety of reductants are also dependent on T, pH, [∑SO₄^2?], and [∑S^2?], and appear to be fast enough to become geochemically important at temperatures above about 200°C.  相似文献   

High temperature heating of the Allende meteorite     

Kenji Notsu  Naoki Onuma  Norimasa Nishida  Hiroshi Nagasawa 《Geochimica et cosmochimica acta》1978,42(6):903-907

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Resonance capacity method for earthquake response analysis of hysteretic structures     

Minoru Yamada  Hiroshi Kawamura 《地震工程与结构动力学》1980,8(4):299-313

The Resonance Capacity Method is proposed for the earthquake response analysis of hysteretic structures. Resonance Capacity is a physical quantity of structures which is related to the hysteretic energy absorbed by structures in one cycle and is equated to the acceleration, velocity and displacement amplitudes α₀, d₀ and d₀ of earthquake ground motions at resonance.¹ According to the idealized trapezoidal approximation of earthquake ground motions in the logarithmic period–velocity plane as proposed by Veletsos and Newmark,⁸ the Resonance Capacity property applies in each period range, short, medium and long, where α₀, v₀ and d₀ respectively are approximately constant. In the medium range of periods, the energy dissipated in hysteretic loops and the deformation amplitudes of a single-degree system with elasto–plastic force–deformation relationships are calculated for the case of El Centro 1940, 18 May earthquake, by this Resonance Capacity Method. The result is compared with results from conventional numerical response analyses obtained by Berg and Thomaides,¹⁴ Kato and Akiyama¹² and Veletsos and Newmark,⁸ and the general agreement is seen to be good. Therefore, it may be possible to apply this Resonance Capacity Method over the entire range of periods. By means of this method the earthquake response analysis of hysteretic systems can be performed easily, and the hysteretic energy and fatigue characteristics of structures may be taken into account directly, up to the point of fracture.  相似文献   

Trace element in igneous petrology | C.J. Allègre and S.R. Hart (Editors), 1978. A Volume in Memory of Paul W. Gast. Developments in Petrology, 5. Elsevier,Amsterdam, 272 pp., Dfl. 121.00, $ 49.95     

Hiroshi Nagasawa 《Earth》1979,15(1):79-80

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Undrained dynamic-loading ring-shear apparatus and its application to landslide dynamics   总被引：26，自引：17，他引：9  

Kyoji Sassa  Hiroshi Fukuoka  Gonghui Wang  Naohide Ishikawa 《Landslides》2004,1(1):7-19

Landslides are gravitational mass movements of rock, debris or earth. Some move very slowly, thus conforming to the field of statics, but some move rapidly. Study of the initiation and motion of rapid landslides needs to develop Landslide Dynamics involving dynamic loading and dynamic generation/dissipation of excess pore-water pressure. New developments in science can be facilitated by new technological advances. This study aimed to develop a new apparatus that can geotechnically simulate the formation of the shear zone and the following long and rapid shear displacement that occurs in high-velocity landslides. Professor K. Sassa and his colleagues at DPRI (Disaster Prevention Research Institute), Kyoto University, have worked to develop an undrained dynamic-loading ring-shear apparatus for this purpose. A series of different types of apparatus (DPRI-3, 4, 5, 6, 7) have been developed from 1992 to the present. This paper describes the development of this apparatus and its application to the study of earthquake-induced landslides and the latest landslide-triggered debris flow in Japan. Also, tests of the latest version (DPRI-7) with a transparent shear box for direct observation of the shear zone during a rapid shearing are described.  相似文献   

Location and parameters of a microwave millisecond spike event   总被引：1，自引：0，他引：1  

Guangli?HuangEmail author  Hiroshi?Nakajima 《Astrophysics and Space Science》2005,295(4):423-442

A typical microwave millisecond spike event on November 2, 1997 was observed by the radio spectrograph of National Astronomical Observatories (NAOs) at 2.6–3.8 GHz with high time and frequency resolution. This event was also recorded by Nobeyama Radio Polarimeters (NoRP) at 1–35 GHz and Radio Heliograph (NoRH) at 17 GHz. The source at 17 GHz is located in one foot-point of a small bright coronal loop of YOHKOH SXT and SOHO EIT images with strong photospheric magnetic field in SOHO MDI magnetograph. It is assumed that the electron cyclotron maser instability and gyro-resonance absorption dominate, respectively, the rising and decay phase of the spike event. For different harmonic number of gyro-frequency or magnetic field strength, a fitting program with free plasma parameters is used to minimize the difference between the observational and theoretical values of the exponential growth and decay rates for a given spike. The plasma parameters at third harmonic number are more comparable to their typical values in solar corona. Hence, it is able to provide a diagnosis for the source parameters (magnetic field, density, and temperature), the properties of radiations (wave vector and propagation angle), and the properties of non-thermal electrons (density, pitch angle, and energy). The results are also comparable with the diagnosis of the gyro-synchrotron radiation model, the frequency drift rates and a dipole magnetic field model, as well as the YOHKOH SXT and SOHO MDI data. This study is supported by the NFSC project nos. 10333030 and 10273025, and “973” program with no. G2000078403.  相似文献   

Pressure dependence on partition coefficients for trace elements between olivine and the coexisting melts     

Hiroshi Taura  Hisayoshi Yurimoto  Kei Kurita  Shigeho Sueno 《Physics and Chemistry of Minerals》1998,25(7):469-484

Partition coefficients between olivine and melt at upper mantle conditions, 3 to 14 GPa, have been determined for 27 trace elements (Li, Be, B, Na, Mg, Al, Si, P, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Rb, Sr, Y, Zr, Cs, Ba, La and Ce) using secondary-ion mass-spectrometry (SIMS) and electron-probe microanalysis (EPMA). The general pattern of olivine/melt partitioning on Onuma diagrams resembles those reported previously for natural systems. This agreement strongly supports the argument that partitioning is under structural control of olivine even at high pressure. The partition coefficients for mono- and tri-valent cations show significant pressure dependence, both becoming larger with pressure, and are strongly correlated with coupled substitution into cation sites in the olivine structure. The dominant type of trace element substitution for mono- and tri-valent cations into olivine changes gradually from (Si, Mg)↔(Al, Cr) at low pressure to (Si, Mg)↔(Al, Al) and (Mg, Mg)↔(Na, Al) at high pressure. The change in substitution type results in an increase in partition coefficients of Al and Na with pressure. An inverse correlation between the partition coefficients for divalent cations and pressure has been observed, especially for Ni, Co and Fe. The order of decreasing rate of partition coefficient with pressure correlates to strength of crystal field effect of the cation. The pressure dependence of olivine/melt partitioning can be attributed to the compression of cation polyhedra induced by pressure and the compensation of electrostatic valence by cation substitution. Received: March 6, 1997 / Revised, accepted: March 12, 1998  相似文献   

Simultaneous multifrequency observations of an eruptive prominence at millimeter wavelengths     

Yoshihisa Irimajiri  Toshiaki Takano  Hiroshi Nakajima  Kiyoto Shibasaki  Yoichiro Hanaoka  Kiyoshi Ichimoto 《Solar physics》1995,156(2):363-375

Radio images and spectra of an eruptive prominence were obtained from simultaneous multifrequency observations at 36 GHz, 89 GHz, and 110 GHz on May 28, 1991 with the 45-m radio telescope at Nobeyama Radio Observatory (NRO), the National Astronomical Observatory, Japan (NAOJ). The radio spectra indicated that the optical depth is rather thick at 36 GHz whereas it is thin at 89 and 110 GHz. The H data, taken at Norikura Solar Observatory, NAOJ, suggest that the eruption of an active region filament was triggered by an H flare. The shape and position of the radio prominence generally coincided with those of H images. The radio emission is explained with an isothermal cool thread model. A lower limit for the electron temperature of the cool threads is estimated to be 6100 K. The range of the surface filling factors of the cool threads is 0.3–1.0 after the H flare, and 0.2–0.5 in the descending phase of the eruptive prominence. The column emission measure and the electron number density are estimated to be of the order of 10²⁸ cm^–5 and 10¹⁰ cm^–3, respectively. The physical parameters of a quiescent prominence are also estimated from the observations. The filling factors of the eruptive prominence are smaller than those of the quiescent prominence, whereas the emission measures and the electron densities are similar. These facts imply that each cool thread of the prominence did not expand after the eruption, while the total volume of the prominence increased.  相似文献   

Fast Oxidation Reaction of Nitrite by Dissolved Oxygen in the Freezing Process in the Tropospheric Aqueous Phase     

Norimichi Takenaka  Tohru Daimon  Akihiro Ueda  Keiichi Sato  Masaru Kitano  Hiroshi Bandow  Yasuaki Maeda 《Journal of Atmospheric Chemistry》1998,29(2):135-150

Nitrite oxidation in the tropospheric aqueous phase by freezing was evaluated by freezing a field sample. Nitrite oxidation by dissolved oxygen in the freezing process is much faster than by other oxidation processes, such as reactions with ozone, hydrogen peroxide or dissolved oxygen in an aqueous solution at pHs 3 to –6. At pH 4.5 and 25°C, the lifetime of nitrite in the aqueous phase is ca. 1 hr in oxidation by ozone (6×10^-10 mol dm^-3), ca. 10 hr in oxidation by H₂O₂ (2×10^-4 mol dm^-3), and 7.5 hr (Fischer and Warneck, 1996) in photodissociation at midday in summer. Under the same conditions at a temperature below 0°C, the lifetime of nitrite in the freezing process is estimated as ca. 2 sec when the droplets are frozen within a second. The reaction by freezing is affected by the presence of salts, such as NaCl or KCl, or orgnaic compounds, such as methanol or acetone. The results of freezing a field rain or fog sample showed that nitrite oxidation proceeds below pH 6, and the conversion ratio of nitrate from nitrite increases with decreasing pH. The oxidation of nitrite by freezing was also observed in freezing fog particles generated by an ultrasonic humidifier. The ratios of the concentrations of ions in the winter sample to those in the summer sample (or those in the fog sample) were almost the same values. However, the concentration of nitrite in the winter sample was lower than that estimated by the ratios of other ions. From the present study, it seems that the freezing process plays an important role in the nitrite sink process in the tropospheric aqueous phase.  相似文献